Synthesis, Spectral and Structural Studies, and an Evaluation of the Hydrogen Bonding of Some Phenylhydrazone
| dc.contributor.author | Kaberia, Festus | |
| dc.contributor.author | Brian, Vickery | |
| dc.date.accessioned | 2014-08-08T09:45:41Z | |
| dc.date.available | 2014-08-08T09:45:41Z | |
| dc.date.issued | 1980 | |
| dc.description | DOI: 10.1039/P29800001622 | en_US |
| dc.description.abstract | A series of 46 phenylhydrazones, soms novel, containing a variety of structural types has been synthesised. These have been studied by lH n.m.r. and i.r. spectroscopy with respect to potential inter- and intra-mslecular hydrogen bonding. ortho-Nitro or -carbony1 groups form strong hydrogen bonds to the imino-group which are readily observed by lH n.m.r. but not by i.r. spectroscopy. ' Terminal ' carbonyl groups also form strong hydrogen bonds to the imino-group and these can be detected by both i.r. and lH n.m.r. spectroscopy. When both ortho-nitro- or -carbony1 groups and ' terminal ' carbonyl groupsare present the imino hydrogen atom is doubly hydrogen bonded and this is apparent in the lH n.m.r. spectrum. The formation of an intramolecular hydrogen bond in the phenyl- hydrazone prevents the formation of an interm Aecular hydrogen bond between the phenylhydrazone and a polar solvent | en_US |
| dc.identifier.citation | Journal of the Chemical Society, Perkin Transactions 2 Issue 11, 1980 | en_US |
| dc.identifier.issn | 1472-779X | |
| dc.identifier.other | 1364-5471 | |
| dc.identifier.uri | http://ir-library.ku.ac.ke/handle/123456789/10854 | |
| dc.language.iso | en | en_US |
| dc.publisher | Royal Society of Chemistry | en_US |
| dc.title | Synthesis, Spectral and Structural Studies, and an Evaluation of the Hydrogen Bonding of Some Phenylhydrazone | en_US |
| dc.type | Article | en_US |