A Structural Investigation of the D2O Solvated, Acetone Solvated and Nonsolvated 1,4-Diazabicyclo[2.2.2]octane Complexes of the Half Sandwich Moiety [(ç5 -C5H5)(CO)2Fe]
| dc.contributor.author | Changamu, E. O. | |
| dc.contributor.author | Cyprian M. M’thiruainea | |
| dc.contributor.author | Holger B. Friedricha | |
| dc.contributor.author | Bernard Omondia | |
| dc.date.accessioned | 2015-03-25T11:49:49Z | |
| dc.date.available | 2015-03-25T11:49:49Z | |
| dc.date.issued | 2013 | |
| dc.description.abstract | Two new solvates of the dinuclear salt {(ç5-C5H5)(CO)2Fe}2(ì-DABCO)](BF4)2 (DABCO = 1,4-diazabicyclo[2.2.2]octane); 1 (D2O solvate) and 2 (acetone solvate), and the mononuclear salt [(ç5-C5H5)(CO)2Fe(DABCO)]BF4, 3, have been synthesized and structurally characterized. The D2O solvate, 1 forms crystals in the triclinic space group P1, the acetone solvate forms crystals in the monoclinic P21/c space group, while the unsolvated mononuclear salt, 3, forms crystals in the orthorhombic P212121 space group. The respective unit cell parameters are: Compound 1, a = 7.66300(10) Å, b = 12.3133(2) Å, c = 13.9629(2) Å, á = 69.179(1) °, â= 77.114(1) ° and ã = 84.282(1) °; Compound 2, a = 17.3633(3) Å, b = 14.1688(3) Å, c = 11.3542(2) Å, â = 99.344(1) °; Compound 3, a = 8.9936(2) Å, b = 10.8949(3) Å, c = 15.3417(4) Å. The DABCO ligand adopts a twisted conformation with N-C-C-N torsion angles ranging between –21.05(12) to –19.31(12) ° and 15.3(2) –15.7(2) ° in 1 and 2, respectively, whereas in 3, the CH2 groups of each NCH2CH2N moiety are almost eclipsed, the torsion angles ranging from –2.89(18) to –1.50(16) | en_US |
| dc.identifier.citation | S. Afr. J. Chem., 2013, 66, 237–243 | en_US |
| dc.identifier.issn | 0379-4350 | |
| dc.identifier.other | 1996-840X | |
| dc.identifier.uri | http://www.scielo.org.za/pdf/sajc/v66/38.pdf | |
| dc.identifier.uri | http://ir-library.ku.ac.ke/handle/123456789/12424 | |
| dc.language.iso | en | en_US |
| dc.publisher | Sabinet | en_US |
| dc.subject | Cyclopentadienyliron dicarbonyl complex | en_US |
| dc.subject | 1,4-diazabicyclo[2.2.2]octane (DABCO) | en_US |
| dc.subject | X-ray crystallography | en_US |
| dc.title | A Structural Investigation of the D2O Solvated, Acetone Solvated and Nonsolvated 1,4-Diazabicyclo[2.2.2]octane Complexes of the Half Sandwich Moiety [(ç5 -C5H5)(CO)2Fe] | en_US |
| dc.type | Article | en_US |
Files
Original bundle
1 - 1 of 1
Loading...
- Name:
- A Structural Investigation of the D2O Solvated......pdf
- Size:
- 1010.6 KB
- Format:
- Adobe Portable Document Format
- Description:
- Full text Article
License bundle
1 - 1 of 1
No Thumbnail Available
- Name:
- license.txt
- Size:
- 1.71 KB
- Format:
- Item-specific license agreed upon to submission
- Description: