Hassanali, AhmedAcott, B.Beckwith, A. L. J.2014-03-042014-03-041968Australian Journal of Chemistry 21(1) 197 - 205http://ir-library.ku.ac.ke/handle/123456789/9180doi:10.1071/CH9680197Treatment of primary carboxamides with lead tetraacetate in benzene-alcohol mixtures or neat alcohol affords a convenient, flexible, and efficient method for the preparation of N-substituted carbamic acid esters. The reaction is applicable to amides and alcohols of a wide range of structural types including compounds containing oleflnic, ester, aromatic, and other reactive functions. The reaction mechanism appears to involve intermediate formation of isocyanates.enReactions of Lead Tetraacetate. II. Formation of Carbamic Acid Esters from Primary CarboxamidesArticle