Synthesis, Characterization and Electrochemistry of Heterobimetallic Complexes Containing Molybdenum(ii) Nitrosyl and Manganese(ii)-schiff Base Centers

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dc.contributor.authorOdhiambo, R.
dc.contributor.authorMuthakia, G. K.
dc.contributor.authorKagwanja, S. M.
dc.date.accessioned2014-01-21T09:40:59Z
dc.date.available2014-01-21T09:40:59Z
dc.date.issued2010
dc.description.abstractNew complexes derived from the reaction of Mo(NO)T p * Cl 2 ; T p * = tris(3,5-dimethylpyrazolyl) borate with a series of manganese(II) Schiff bases have been synthesized. Characterization by UV, IR, MS and elemental analysis support their formulations. Cycl ic and differential pulse voltammograms of manganes e(II) Schiff base monometallic complexes exhibit one redu ction peak which may be associated with the reducti on of the manganese(II) center. In CH 3 CN solutions, the molybdenum(II)-manganese(II) bime tallic complexes showed two reversible reduction peaks which are associated with the reduction of the molybdenum and manganese centers. In CH 2 Cl 2 , only the reduction of molybdenum(II) center exhib ited reversibility while the reduction of manganese(II) center was irreversible. These observ ations demonstrate that reduction potentials for bi metallic complexes are solvent dependent.en_US
dc.identifier.citationBull. Chem. Soc. Ethiop. 2010 , 24(1), 47-58.en_US
dc.identifier.issn1011-3924
dc.identifier.urihttp://ir-library.ku.ac.ke/handle/123456789/8745
dc.language.isoenen_US
dc.publisherChemical Society of Ethiopiaen_US
dc.subjectTetradentate N,N’,O,O,en_US
dc.subjectSchiff base ligandsen_US
dc.subjectMonomet allic manganese(II) Schiff base complexesen_US
dc.subjectBimetallicen_US
dc.subjectMn(II)-Mo(NO)T p * Cl 2 [T p * = tris(3,5-dimethylpyrazolyl) borate] complexesen_US
dc.titleSynthesis, Characterization and Electrochemistry of Heterobimetallic Complexes Containing Molybdenum(ii) Nitrosyl and Manganese(ii)-schiff Base Centersen_US
dc.typeArticleen_US
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